Solvophobic interaction
WebJan 1, 1972 · Interaction between surfaces with solvophobicity or solvophilicity immersed in solvent: Effects due to addition of solvophobic or solvophilic solute J. Chem. Phys. 118 , … WebNature
Solvophobic interaction
Did you know?
WebThe relation between a solvophobic interaction (SI) and a solute–solute radial distribution function is discussed. The SI is defined as the difference between the indirect part of the solute–solute potential of the mean force in a solvent and that in a “homomorphic” solvent. It was calculated using the RHNC-like integral equation of RISM-1 for a dilute solution of … WebDec 15, 2007 · A mechanism of solvophobic interactions has been suggested based on the elasticity of the spatial H-bond network of a solvent. This network pushes out solvophobic …
WebAug 20, 2024 · Here the formation of porous and non-porous polymorphs in different solvents is shown to depend on a solvophobic effect driven by dispersion interactions. … WebOct 19, 2014 · Thermodynamic analysis of the experimental data showed that the macroscopic solvophobic interactions were enthalpic but exhibited significant enthalpy …
WebJan 10, 2006 · Abstract. A mechanism of solvophobic interactions based on the concept that the elastic spatial hydrogen-bond network forces out dissolved solvophobic species … WebThe results show that the solvent association alone does not bring about a significant solvophobic interaction between solute molecules, if compared with the hard sphere …
WebNov 21, 2013 · The major difference in this particular study is the aim of trying to distinguish the very weak solute–solute dispersion effects from the omnipresent solvation or solvophobic effects 6.The ...
WebOct 19, 2014 · Thermodynamic analysis of the experimental data showed that the macroscopic solvophobic interactions were enthalpic but exhibited significant enthalpy-entropy compensations. The enthalpy decreases ... green bug identificationWebOct 11, 2012 · Thermodynamic analysis of the experimental data showed that the macroscopic solvophobic interactions were enthalpic but exhibited significant enthalpy-entropy compensations. greenbugh tylerWebSep 7, 2024 · Another example is ionic liquids (IL), which are receiving increasing attention over the past few years due to environmental awareness; the CMC values of surfactants in IL significantly increased because of the decreased electrostatic interactions between headgroups and the reduced solvophobic interaction between the alkyl chain and IL … flower that blooms in moonlightWebMay 20, 2011 · That is, the weaker the ionic interaction is, the less ordered the arrangement of IL molecules around hydrocarbon chains, and hence, the weaker the solvophobic interaction becomes. Comparing the three anion species, the ionic interaction with bmim cation would become weaker in the order of BF − 4 > PF − 6 > CF 3 SO − 3 , because the … flower that blooms onceWebReplacement of weaker interactions between a moderately polar solute and a strongly polar mobile phase by mutual interactions between strongly polar molecules of the mobile … flower that blooms in the early fallWebA droplet of water forms a spherical shape, minimizing contact with the hydrophobic leaf. The hydrophobic effect is the observed tendency of nonpolar substances to aggregate in … flower that blooms for one dayWebSep 29, 1976 · Solute interaction with nonpolar stationary phases in liquid chromatography is examined on the basis of the solvophobic theory. The chromatographic process is … green bug in cauliflower