Web作者以邻甲基碘苯为底物，在1当量Bu4NCl存在下进行羰基化反应，并使用2,6-二异丙基苯胺作为原位酰氯的捕获剂。 ... 2和{Ir[dF(CF3)ppy]2(dtbpy)}PF6时，能够以34% ... WebGordon Research Conference: Electron Donor-Acceptor August 2, ... [Ir[dF(CF3)ppy]2(dtbpy)]X. Time-resolved dielectric-loss experiments show how counter-ion identity influences excited-state charge ...

Enzyme-like C–H Oxidation of Glucosides Promoted by Visible Light

WebThe methanolic fraction was evaporated, resuspended in DCM (50 mL), filtered, and evaporated under reduced pressure, resulting in a yellow-green solid (recovered (Ir[dF(CF3)ppy] 2 (dtbpy))PF 6, 489 mg) that was reused in the next 8 h experiment after the addition of 50 mg of fresh (Ir[dF(CF3)ppy] 2 (dtbpy))PF 6. The procedure was repeated … WebThe mixture was heated at 150 °C for 15 h and then cooled. The cooled reaction mixture was washed hexane (3 10 mL) and mixture was heated to 85 °C for 5 min to remove residual hexane. Aqueous ammonium hexafluorophosphate (sat. solution) was added to the reaction mixture causing the iridium-PF 6 salt to precipitate,which was filtered, dried ... fishing upper delaware river

【有机】韩国科学技术院Sungwoo Hong课题组Angew：可见光诱 …

WebApr 14, 2024 · Here we show that dynamic ion-pair reorganization controls the reactivity of a photoredox catalyst, [Ir [dF (CF 3 )ppy] 2 (dtbpy)]X. Time-resolved dielectric-loss experiments show how counter-ion identity influences excited-state charge distribution, evincing large differences in both the ground- and excited-state dipole moment depending … http://www.studyofnet.com/135712210.html WebAlfa Chemistry offers (Ir[dF(CF3)ppy]2(dtbpy))PF6 for experimental / research use. View information & documentation regarding (Ir[dF(CF3)ppy]2(dtbpy))PF6, including CAS, structure & more. cancer stress waiting